18060 Araldite 502 MSDS - Ted Pella, Inc.

Material Safety Data Sheet

Product No. 18060 Araldite 502

Issue Date (06-15-06)

Review Date (09-21-06)

Section 1: Product and Company Identification

Product Name: Araldite 502

Synonym: Bisphenol A Diglycidyl Ether. Chemical name: Phenol, 4,4’-(1-Methylethylidene) Bis-Polymer with (Chloromethyl) Oxirane

or (Chloromethyl)Oxirane, 4,4'-(1-Methylethylidene) Bisphenol Copolymer Dibutyl Phthalate. Chemical name: 1,2-Benzenedicarboxyllic Acid, Dibutyl Ester

Company Name

Ted Pella, Inc. and PELCO International, P.O. Box 492477, Redding, CA 96049-2477
Domestic Phone (800) 237-3526 (Mon-Thu. 6:00AM to 4:30PM PST; Fri 6:00AM to 4:00PM PST)

International Phone (01) (530) 243-2200 (Mon-Thu. 6:00AM to 4:30PM PST; Fri 6:00AM to 4:00PM PST)

Chemtrec Emergency Number 1-800-424-9300 24 hrs a day.

Section 2: Composition / Information on Ingredients

Principle Hazardous Component(s)
(chemical and common name(s)) (Cas. No)

OSHA
PEL

mg/m3

ACGIH
TLV mg/m3

NTP

IARC

OSHA
regulated

Bisphenol A epoxy resin

(25068-38-6)

~84

Dibutyl phthalate

(84-74-2)

Section 3: Hazard Identification
Emergency overview

Appearance: Light colored liquid with slight aromatic odor.

Immediate effects: ND.

Potential health effects

Primary Routes of entry: Dermal contact, inhalation.
Signs and Symptoms of Overexposure: Eye and respiratory irritation and allergic skin reactions. May also cause nausea, vertigo, photophobia and blood and protein in the urine from ingesting a large single dose.
Eyes: Irritant.

Skin: None

Ingestion: ND

Inhalation: Irritant.

Chronic Exposure: In animal studies this product has affected the testes, female reproductive capacity and the developing fetus. May cause skin sensitization and irritation. May have effect on reproduction and the developing fetus. Avoid contact with eyes, skin and clothing. Avoid breathing vapor, mist or spray. Use only with adequate ventilation.

Chemical Listed As Carcinogen Or Potential Carcinogen: Epichlorohydrin (trace).

See Toxicological Information (Section11)

Potential environmental effects

See Ecological Information (Section 12)

Section 4: First Aid Measures
If accidental overexposure is suspected

Eye(s) Contact: Immediately flush eyes with water for at least 15 minutes with running water. Hold eyelids apart to ensure rinsing of the entire eye surface and lids with water. Get immediate medical attention.

Skin Contact: For skin contact, wipe away excess material with dry towel. Then wash affected areas with plenty of water and soap if available, for several minutes. Get immediate attention if irritation occurs. Promptly remove wet contaminated non-impervious clothing. Wash clothing before reuse.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. Get immediate medical attention. If breathing is difficult, transport to medical care and, if available, give supplemental oxygen.

Ingestion: If swallowed, give at least 3-4 glasses of water but do not induce vomiting. Do not give anything by mouth to an unconscious or convulsing person.

Note to physician

Treatment: ND

Medical Conditions generally Aggravated by Exposure: Allergy, eczema or skin conditions.

Section 5: Fire Fighting Measures
Flash Point: 400°F (closed cup)
Flammable Limits: ND

Auto-ignition point: ND
Fire Extinguishing Media: Carbon dioxide, foam, dry chemical, water spray.
Special Fire Fighting Procedures: Use self-contained breathing apparatus.
Unusual Fire and Explosion Hazards: ND

Hazardous combustion products: Decomposition and combustion products may be toxic.

DOT Class: 9

Section 6: Accidental Release Measures
Steps to be Taken in Case Material is Released or Spilled: Absorb with sand or other absorbent material. Shovel into closeable container for disposal. Wear protective equipment. Flush contaminated area with water.
Waste Disposal Methods: Dispose of waste according to Federal, State and Local Regulations.

Section 7: Handling and Storage
Precautions to be Taken in Handling and Storage: Avoid contact with eyes, skin and clothing. Avoid breathing vapor, mist or spray. Use only with adequate ventilation. Wash exposed skin after handling. Store in cool, dry area in closed containers.

Storage temperature: Cool dry area.

Storage Pressure: ND

Section 8: Exposure Controls / Personal Protection
Engineering Controls

Ventilation required: Good general mechanical ventilation required.

Personal Protection Equipment

Respiratory protection: Organic chemical cartridge respirator, if needed.

Protective gloves: Wear impervious gloves.
Skin protection: Appropriate equipment to prevent skin contact. Use of a barrier cream is recommended.
Eye protection: Wear splash-proof chemical goggles or complete face shield.
Additional clothing and/or equipment: Wear appropriate equipment to prevent eye or skin contact.

Exposure Guidelines

See Composition/Information on Ingredients (Section2)

Section 9 Physical and Chemical Properties
Appearance and Physical State: Light colored liquid.

Odor (threshold): Slight aromatic odor.

Specific Gravity (H2O=1): 1.13

Vapor Pressure (mm Hg): ND

Vapor Density (air=1): ND

Percent Volatile by volume: ND

Evaporation Rate (butyl acetate=1):ND

Boiling Point: >200°C

Freezing point / melting point: ND
pH: ND
Solubility in Water: Insoluble.
Molecular Weight: NA

Section 10: Stability and Reactivity
Stability: Stable.
Conditions to Avoid: Elevated temperatures. Strong acids or bases in bulk.

Materials to Avoid (Incompatibility): Strong oxidizing agents and nitrates.
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, aldehydes.
Hazardous Polymerization: Will not occur.

Section 11: Toxicological Information

Results of component toxicity test performed: Dibutyl phthalate: Rat, Oral LD50: 8000 mg /kg. Rabbit, Dermal LD50: >4-6 g/kg. Results: Rabbits, Non-irritating to skin. Eye irritant.

Moderate sensitizer. Respiratory irritant.

Human experience: ND

This product does contain any compounds listed by NTP or IARC or regulated by OSHA as a carcinogen.

Section 12: Ecological Information

Ecological Information: Dibutyl phthalate is listed as marine pollutant.

Chemical Fate Information: ND

Section 13 Disposal Considerations

RCRA 40 CFR 261 Classification: ND on mixture. Dibutyl phthalate, 84-74-2, Waste Code U069. Oxirane, (chloromethyl)- , 106-89-8, Waste Code U041.

Federal, State and local laws governing disposal of materials can differ. Ensure proper disposal compliance with proper authorities before disposal.

Section 14: Transportation Information

US DOT Information: Proper shipping name: Environmentally hazard substance, liquid, n.o.s. (Dibutyl phthalate)

Hazard Class: 9

Packaging group: III

UN Number: UN 3082

Limitations: DOT regulated only for non-bulk shipments in containers greater than or equal to 62.5lbs. Dibutyl Phthalate: RQ = 10 lbs (4.54 kg).

IATA: Proper shipping name: Environmentally hazard substance, liquid, n.o.s. (Dibutyl phthalate)

Hazard Class: 9

Packing group: III

UN Number: UN 3082

Limitations: DOT regulated only for non-bulk shipments in containers greater than or equal to 62.5lbs. Dibutyl Phthalate: RQ = 10 lbs (4.54 kg).

Domestic shipments only:

IMO: Proper shipping name: Environmentally hazard substance, liquid, n.o.s. (Dibutyl phthalate)

Class: 9

UN Number: UN 3082

Packing group: III

EMS: ND

MFAG: ND

Marine Pollutant: Yes, Dibutyl phthalate.

Canadian TDG: ND

IMDG Page: ND

Limitations: ND

Section 15: Regulatory Information

United States Federal Regulations

MSDS complies with OSHA’s Hazard Communication Rule 29, CFR 1910.1200.

SARA: ND

SARA Title III: This product is (or contains) a toxic chemical for routine annual 'Toxic Chemical Release Reporting' under Sec. 313 (40 CFR 372). 16.0000%; 87-74-2; Dibutyl Phthalate.

RCRA: Not a hazardous waste under RCRA (40 CFR 261).

TSCA: Chemical components listed on TSCA inventory:

TSCA Export Notification: This product contains chemical(s) which is (are) regulated by TSCA 12(B) regulation and it is required that proper export notification shall be sent to EPA prior to shipping out of the United States of America.

Chemical name: 1, 2-Benzenedicarboxylic Acid, Dibutyl Ester. CAS#: 000084-74-2. Chemical name: Bisphenol A Diglycidyl Ether. CAS#: 001675-54-3.

CERCLA: Dibutyl Phthalate: RQ = 10 lbs (4.54 kg).

State Regulations

California Proposition 65: WARNING! This product contains a chemical known to the state of California to cause cancer and birth defects or other reproductive harm. Chemical Name: Epichlorohydrin (106-89-8). Trace amount. Dibutyl phthalate (87-74-2).

International Regulations

Canada WHMIS: All components included on the domestic substance list (DSL)

Europe EINECS Numbers: ND

Section 16: Other Information

Label Information: ND

European Risk and Safety Phrases: ND

European symbols needed: ND

Canadian WHMIS Symbols: ND

HMIS® Hazard Rating: Health: 2; Fire: 1; Reactivity: 0
(0=least, 1=Slight, 2=Moderate, 3=High, 4=Extreme)

Abbreviations used in this document

NE= Not established

NA= Not applicable

NIF= No Information Found

ND= No Data

Disclaimer
Ted Pella, Inc. makes no warranty of any kind regarding the information furnished herein. Users should independently determine the suitability and completeness of information from all sources. While this data is presented in good faith and believed to be accurate, it should be considered only as a supplement to other information gathered by the user. It is the User's responsibility to assure the proper use and disposal of these materials as well as the safety and health of all personnel who may work with or otherwise come in contact with these materials.

MSDS Form 0013F1 V2